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Syngas production from heavy liquid fuel reforming in inert porous media 10.17863/CAM.13997 Pastore, Andrea In the effort to introduce fuel cell technology in the field of decentralized and mobile power generators, a hydrocarbon reformer to syngas seems to be the way for the market uptake. In this thesis, a potential technology is developed and investigated, in order to convert commercial liquid fuel (diesel, kerosene and biodiesel) to syngas. The fundamental concept is to oxidise the fuel in a oxygen depleted environment, obtaining hydrogen and carbon monoxide as main products of the reaction. In order to extend the flammability limit of hydrocarbon/air mixtures, the rich combustion experiments have been carried out in a two-layer porous medium combustor, which stabilises a flame at the matrix interface and recirculates the enthalpy of the hot products in order to enhance the reaction rates at ultra-rich equivalence ratio. This thesis demonstrates the feasibility of the concept, by exploring characteristic parameters for a compact, reliable and cost effective device. Specifically, a range of equivalence ratios, thermal loads and porous materials have been examined. n-heptane was successfully reformed up to an equivalence ratio of 3, reaching a conversion efficiency (based on the lower heating value of H2 and CO over the fuel input) up to 75% for a packed bed of alumina beads. Thermal loads from P=2 to 12 kW at phi=2.0 demonstrated that heat losses can be reduced to 10%. Similarly, diesel, kerosene and bio-diesel were reformed to syngas in a Zirconia foam burner with conversion efficiency over 60%. The effect of different burners, thermal loads and equivalence ratios have also been assessed for these commercial fuels, leading to equivalent conclusions. A preliminary attempt to reduce the content of CO and hydrocarbons in the reformate has been also performed using commercial steam reforming and water-gas shift reaction catalysts, obtaining encouraging results. Finally, soot emission has been assessed, demonstrating particle formation for all the fuels above phi=2.0, with biodiesel showing the lowest soot formation tendency among all the fuels tested. University of Cambridge 2010-11-16 Thesis Doctoral Doctor of Philosophy (PhD) eng http://www.dspace.cam.ac.uk/handle/1810/237704 https://www.repository.cam.ac.uk/handle/1810/237704 https://apollo8-f-pro.lib.cam.ac.uk/bitstreams/8d250bd1-4521-4079-a0d1-5621325fcd67/download 32aa03c9bd7f8cb3f68746e3df136f89 https://apollo8-f-pro.lib.cam.ac.uk/bitstreams/ad74adab-aa00-46c7-b7ab-b93c31546e70/download 48dcdf38f646da27e5e4bc6c1893d4fc https://www.rioxx.net/licenses/all-rights-reserved/ Syngas production Rich combustion Porous burner Superadiabatic combustion Fuel reforming