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   <front>
      <journal-meta>
         <journal-id journal-id-type="publisher-id">nz</journal-id>
         <journal-id journal-id-type="coden">aelccp</journal-id>
         <journal-title-group>
            <journal-title>ACS Energy Letters</journal-title>
            <abbrev-journal-title>ACS Energy
Lett.</abbrev-journal-title>
         </journal-title-group>
         <issn publication-format="print">2380-8195</issn>
         <issn publication-format="electronic">2380-8195</issn>
         <publisher>
            <publisher-name>American Chemical Society</publisher-name>
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         <article-id pub-id-type="doi">10.1021/acsenergylett.2c02352</article-id>
         <article-categories>
            <subj-group subj-group-type="document-type-name">
               <subject>Letter</subject>
            </subj-group>
         </article-categories>
         <title-group>
            <article-title>The Electronic Disorder Landscape of Mixed Halide
Perovskites</article-title>
         </title-group>
         <contrib-group id="CONTRIB-GROUP-d14e22-autogenerated">
            <contrib contrib-type="author" id="ath1" xlink:type="simple">
               <contrib-id contrib-id-type="paragon-plus" authenticated="true">3650471</contrib-id>
               <contrib-id contrib-id-type="orcid" authenticated="true">https://orcid.org/0000-0003-1630-4052</contrib-id>
               <name name-style="western">
                  <surname>Liu</surname>
                  <given-names>Yun</given-names>
               </name>
               <xref rid="aff1" ref-type="aff"/>
               <xref rid="notes2" ref-type="author-notes"/>
            </contrib>
            <contrib contrib-type="author" id="ath2" xlink:type="simple">
               <contrib-id contrib-id-type="paragon-plus" authenticated="true">6397963</contrib-id>
               <contrib-id contrib-id-type="orcid" authenticated="true">https://orcid.org/0000-0003-0479-5464</contrib-id>
               <name name-style="western">
                  <surname>Banon</surname>
                  <given-names>Jean-Philippe</given-names>
               </name>
               <xref rid="aff2" ref-type="aff"/>
            </contrib>
            <contrib contrib-type="author" id="ath3" xlink:type="simple">
               <contrib-id contrib-id-type="paragon-plus" authenticated="true">6397977</contrib-id>
               <name name-style="western">
                  <surname>Frohna</surname>
                  <given-names>Kyle</given-names>
               </name>
               <xref rid="aff1" ref-type="aff"/>
            </contrib>
            <contrib contrib-type="author" id="ath4" xlink:type="simple">
               <contrib-id contrib-id-type="paragon-plus" authenticated="true">4859842</contrib-id>
               <name name-style="western">
                  <surname>Chiang</surname>
                  <given-names>Yu-Hsien</given-names>
               </name>
               <xref rid="aff1" ref-type="aff"/>
            </contrib>
            <contrib contrib-type="author" id="ath5" xlink:type="simple">
               <contrib-id contrib-id-type="paragon-plus" authenticated="true">6224057</contrib-id>
               <name name-style="western">
                  <surname>Tumen-Ulzii</surname>
                  <given-names>Ganbaatar</given-names>
               </name>
               <xref rid="aff3" ref-type="aff"/>
            </contrib>
            <contrib contrib-type="author" id="ath6" xlink:type="simple">
               <contrib-id contrib-id-type="paragon-plus" authenticated="true">1293325</contrib-id>
               <contrib-id contrib-id-type="orcid" authenticated="true">https://orcid.org/0000-0002-8303-7292</contrib-id>
               <name name-style="western">
                  <surname>Stranks</surname>
                  <given-names>Samuel D.</given-names>
               </name>
               <xref rid="aff1" ref-type="aff"/>
               <xref rid="aff3" ref-type="aff"/>
            </contrib>
            <contrib contrib-type="author" id="ath7" xlink:type="simple">
               <contrib-id contrib-id-type="paragon-plus" authenticated="true">3033046</contrib-id>
               <name name-style="western">
                  <surname>Filoche</surname>
                  <given-names>Marcel</given-names>
               </name>
               <xref rid="aff2" ref-type="aff"/>
               <xref rid="aff4" ref-type="aff"/>
            </contrib>
            <contrib contrib-type="author"
                     corresp="yes"
                     id="ath8"
                     xlink:type="simple">
               <contrib-id contrib-id-type="paragon-plus" authenticated="true">319137</contrib-id>
               <contrib-id contrib-id-type="orcid" authenticated="true">https://orcid.org/0000-0001-6565-6308</contrib-id>
               <name name-style="western">
                  <surname>Friend</surname>
                  <given-names>Richard H.</given-names>
               </name>
               <xref rid="cor1" ref-type="corresp"/>
               <xref rid="aff1" ref-type="aff"/>
            </contrib>
            <aff id="aff1">
               <label>†</label>
               <institution content-type="dept" xlink:type="simple">Cavendish
Laboratory</institution>, <institution-wrap>
                  <institution-id institution-id-type="Ringgold" specific-use="source:pplus">2152</institution-id>
                  <institution xlink:type="simple">University of Cambridge</institution>
               </institution-wrap>, <city>Cambridge</city>
               <postal-code>CB3 0HE</postal-code>, <country>United Kingdom</country>
            </aff>
            <aff id="aff2">
               <label>‡</label>
               <institution content-type="dept" xlink:type="simple">Laboratoire
de Physique de la Matière Condensée, CNRS</institution>, <institution xlink:type="simple">École Polytechnique, Institut Polytechnique
de Paris</institution>, <postal-code>91120</postal-code>
               <city>Palaiseau</city>, <country>France</country>
            </aff>
            <aff id="aff3">
               <label>§</label>
               <institution content-type="dept" xlink:type="simple">Department
of Chemical Engineering &amp; Biotechnology</institution>, <institution xlink:type="simple">University of Cambridge</institution>, <city>Cambridge</city>
               <postal-code>CB3 0AS</postal-code>, <country>United Kingdom</country>
            </aff>
            <aff id="aff4">
               <label>∥</label>
               <institution content-type="dept" xlink:type="simple">Institut
Langevin, ESPCI Paris</institution>, <institution xlink:type="simple">Université
PSL, CNRS</institution>, <postal-code>75005</postal-code>
               <city>Paris</city>, <country>France</country>
            </aff>
         </contrib-group>
         <author-notes>
            <corresp id="cor1">
               <label>*</label>Email: <email xlink:type="simple">rhf10@cam.ac.uk</email>.</corresp>
         </author-notes>
         <pub-date date-type="pub" publication-format="electronic">
            <day>30</day>
            <month>11</month>
            <year>2022</year>
         </pub-date>
         <pub-date date-type="issue-pub">
            <day>13</day>
            <month>01</month>
            <year>2023</year>
         </pub-date>
         <volume>8</volume>
         <issue>1</issue>
         <fpage>250</fpage>
         <lpage>258</lpage>
         <supplementary-material xlink:href="nz2c02352_si_001.pdf"
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         <history>
            <date date-type="received">
               <day>17</day>
               <month>10</month>
               <year>2022</year>
            </date>
            <date date-type="accepted">
               <day>23</day>
               <month>11</month>
               <year>2022</year>
            </date>
            <date date-type="rev-recd">
               <day>18</day>
               <month>11</month>
               <year>2022</year>
            </date>
            <date date-type="asap">
               <day>30</day>
               <month>11</month>
               <year>2022</year>
            </date>
         </history>
         <permissions>
            <copyright-statement>© 2022 The Authors. Published by American Chemical Society</copyright-statement>
            <copyright-year>2022</copyright-year>
            <copyright-holder>The Authors</copyright-holder>
            <ali:free_to_read content-type="AuthorChoicev2" start_date="2022-11-30"/>
            <license xlink:type="simple">
               <ali:license_ref content-type="ccby4_0" start_date="2022-11-30" specific-use="VOR">https://creativecommons.org/licenses/by/4.0/</ali:license_ref>
            </license>
         </permissions>
         <abstract>
            <p>Band gap tunability
of lead mixed halide perovskites makes them
promising candidates for various applications in optoelectronics.
Here we use the localization landscape theory to reveal that the static
disorder due to iodide:bromide compositional alloying contributes
at most 3 meV to the Urbach energy. Our modeling reveals that the
reason for this small contribution is due to the small effective masses
in perovskites, resulting in a natural length scale of around 20 nm
for the “effective confining potential” for electrons
and holes, with short-range potential fluctuations smoothed out. The
increase in Urbach energy across the compositional range agrees well
with our optical absorption measurements. We model systems of sizes
up to 80 nm in three dimensions, allowing us to accurately reproduce
the experimentally observed absorption spectra of perovskites with
halide segregation. Our results suggest that we should look beyond
static contribution and focus on the dynamic temperature dependent
contribution to the Urbach energy.</p>
         </abstract>
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               <funding-source>
                  <institution-wrap>
                     <institution>Simons Foundation</institution>
                     <institution-id institution-id-type="doi">10.13039/100000893</institution-id>
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                     <institution>Simons Foundation</institution>
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               <award-id>601946</award-id>
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            <award-group id="fnd-3">
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                  <institution-wrap>
                     <institution>H2020 European Research Council</institution>
                     <institution-id institution-id-type="doi">10.13039/100010663</institution-id>
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